- low spin-high spin complexes
- Макаров: низкоспиновые-высокоспиновые комплексы
Универсальный англо-русский словарь. Академик.ру. 2011.
low spin-high spin complexes
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Spin transition — The spin transition is one of the most spectacular example of transitionbetween two electronic states in molecular chemistry. The ability of to evolve from a stable to another stable (or metastable) electronicstate in a reversable and detectable… … Wikipedia
Magnetochemistry — is concerned with the magnetic properties of chemical compounds. Magnetic properties arise from the spin and orbital angular momentum of the electrons contained in a compound. Compounds are diamagnetic when they contain no unpaired electrons.… … Wikipedia
coordination compound — Chem. complex (def. 10). Also called coordination complex. * * * ▪ chemistry Introduction any of a class of substances with chemical structures in which a central metal atom is surrounded by nonmetal atoms or groups of atoms, called ligands… … Universalium
Ruthenium(III) chloride — Chembox new Name = Ruthenium(III) chloride Systematic name Ruthenium trichloride Ruthenium(III) chloride > Section1 = Chembox Identifiers CASOther = 10049 08 8 (anhydrous) 14898 67 0 (hydrate) 13815 94 6 (trihydrate) Section2 = Chembox Properties … Wikipedia
d electron count — The d electron count is a chemistry formalism used to describe the electron configuration of the valence electrons of a transition metal center in a coordination complex.[1][2] The d electron count is an effective way to understand the geometry… … Wikipedia
Crystal field theory — (CFT) is a model that describes the electronic structure of transition metal compounds, all of which can be considered coordination complexes. CFT successfully accounts for some magnetic properties, colours, hydration enthalpies, and spinel… … Wikipedia
transition element — Chem. any element in any of the series of elements with atomic numbers 21 29, 39 47, 57 79, and 89 107, that in a given inner orbital has less than a full quota of electrons. Also called transition metal. [1920 25] * * * Any chemical element with … Universalium
Coordination complex — Cisplatin, PtCl2(NH3)2 A platinum atom with four ligands In chemistry, a coordination complex or metal complex, is an atom or ion (usually metallic), bonded to a surrounding array of molecules or anions, that are in turn known as ligands or… … Wikipedia
Complex (chemistry) — The term complex in chemistry is usually used to describe molecules or ensembles formed by the combination of ligands and metal ions. Originally, a complex implied a reversible association of molecules, atoms, or ions through weak chemical bonds … Wikipedia
Transition metal — The term transition metal (sometimes also called a transition element) has two possible meanings: The IUPAC definition[1] states that a transition metal is an element whose atom has an incomplete d sub shell, or which can give rise to cations… … Wikipedia
Ligand field theory — (LFT) describes the bonding in coordination complexes. [Schläfer, H. L.; Gliemann, G. Basic Principles of Ligand Field Theory Wiley Interscience: New York; 1969] It represents an application of molecular orbital theory to transition metal… … Wikipedia
